The former Liverpool boss has agreed to join the Serie A club on a two-year deal after an interim period at Chelsea culminating in Europa League success.
"I am very happy and very satisfied for having committed to a great club with an illustrious heritage like Napoli," he said.
"I understand the history of the city and how the club forms a fundamental part of the culture and traditions of Naples.
"I must confess that I am extremely excited because I can share my passion for football with the fans of Napoli; it is proven that they are very, very special.
"I look forward to experiencing each and every one of the fans of Napoli and their strong support for this project that we will begin."
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